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NaMo2P4O14: A mixed-valence molybdenum phosphate with a tunnel structure

✍ Scribed by K.H. Lii; J.J. Chen; S.L. Wang

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 381 KB
Volume: 78
Category: Article
ISSN: 0022-4596
DOI: 10.1016/0022-4596(89)90142-4

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A new mixed-valent molybdenum monophosphate with a layer structure \(\mathrm{KMo}_{3} \mathrm{P}_{2} \mathrm{O}_{14}\) has been isolated. It crystallizes in the space group \(P 2_{l} / m\) with \(a=8.599\) (2) \(\AA, b=6.392\) (2) \(\AA, c=10.602\) (1) \(\AA\), and \(\beta=111.65(2)^{\circ}\). The l