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Na6(H2O)20 (V10O28)×4H2O, a Novel Polyvanadate(V) with a Three-Dimensional Framework.

✍ Scribed by Hong-Xu Guo; Zhong-Liang Yao

Publisher
John Wiley and Sons
Year
2007
Weight
13 KB
Volume
38
Category
Article
ISSN
0931-7597

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## Abstract For Abstract see ChemInform Abstract in Full Text.

ChemInform Abstract: (NH4)4Na2 [Mo2V2IVV
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Single crystals of the title compound are grown hydrothermally from mixtures of NH 4 VO 3 , Na 2 MoO 4 , H 2 C 2 O 4 , andH 2 O (pH 6; autoclave, 433 K, 4 d). The compound, which crystallizes in the triclinic space group P1 (Z = 1), has a well known decavanadate structure. The centrosymmetric polyan