ChemInform Abstract: (NH4)4Na2 [Mo2V2IVV6VO28]×10H2O.
✍ Scribed by Yan Xu; Ji-Qing Xu; Guo-Yu Yang; Yan Xing; Yong-Hua Lin; Heng-Qing Jia
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Single crystals of the title compound are grown hydrothermally from mixtures of NH 4 VO 3 , Na 2 MoO 4 , H 2 C 2 O 4 , andH 2 O (pH 6; autoclave, 433 K, 4 d). The compound, which crystallizes in the triclinic space group P1 (Z = 1), has a well known decavanadate structure. The centrosymmetric polyanion is built up by eight (V/Mo)O 6 and two VO 6 edge-sharing distorted octahedra. -(XU, YAN;
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