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ChemInform Abstract: (NH4)4Na2 [Mo2V2IVV6VO28]×10H2O.

✍ Scribed by Yan Xu; Ji-Qing Xu; Guo-Yu Yang; Yan Xing; Yong-Hua Lin; Heng-Qing Jia


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Single crystals of the title compound are grown hydrothermally from mixtures of NH 4 VO 3 , Na 2 MoO 4 , H 2 C 2 O 4 , andH 2 O (pH 6; autoclave, 433 K, 4 d). The compound, which crystallizes in the triclinic space group P1 (Z = 1), has a well known decavanadate structure. The centrosymmetric polyanion is built up by eight (V/Mo)O 6 and two VO 6 edge-sharing distorted octahedra. -(XU, YAN;


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