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n - π Interaction studied by carbon-13 NMR spectroscopy

✍ Scribed by Yasuhisa Senda; Jun-ichi Ishiyama; Shin Imaizumi

Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
166 KB
Volume
19
Category
Article
ISSN
0040-4039

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✦ Synopsis

Received in Japan 27 FebxuarJ 1X@; received in UK for publioation 28 March l?%) There are several studies on no-ncc interaction in unsaturated ethers by photoelectron spectrosc0py.l We attempted to examine such interaction by 13C NMR spectroscopy and the spectra of several cyclic allylic alcohols and ethers were measured.

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Conformational equilibria in isomeric me
Conformational equilibria in isomeric methylcyclohexanols studied by 13C NMR spectroscopy
✍ O. A. Subbotin; N. M. Sergeyev; V. N. Chlopkov; N. G. Nikishova; Yu. G. Bundel 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 319 KB

## Abstract The conformational equilibrium constants for isomeric methylcyclohexanols (__cis__‐ and __trans__‐1,2‐, 1,3‐ and 1,4‐methylcyclohexanols) have been determined from peak area measurements in the completely proton decoupled low temperature ^13^C NMR spectra of the individual conformers. T