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Conformational equilibria in isomeric methylcyclohexanols studied by 13C NMR spectroscopy

✍ Scribed by O. A. Subbotin; N. M. Sergeyev; V. N. Chlopkov; N. G. Nikishova; Yu. G. Bundel

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
319 KB
Volume
13
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The conformational equilibrium constants for isomeric methylcyclohexanols (cis‐ and trans‐1,2‐, 1,3‐ and 1,4‐methylcyclohexanols) have been determined from peak area measurements in the completely proton decoupled low temperature ^13^C NMR spectra of the individual conformers. The ^13^C chemical shifts are discussed in terms of the additive model.

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