In the title compound, C 15 H 11 ClN 2 O 2 , the benzene ring is twisted with respect to the phthalimide plane. The molecules are held together by intermolecular OÁ Á ÁHÐN hydrogen bonds, giving rise to a dimeric structure.
N-(tert-Butyloxycarbonylamino)phthalimide
✍ Scribed by Kauffmann, Brice ;Didierjean, Claude ;Brosse, Nicolas ;Jamart-Grégoire, Brigitte ;Aubry, André
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 360 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
An ORTEP-3 (Farrugia, 1997) drawing of (I), showing the atomnumbering scheme and 25% probability displacement ellipsoids.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 180 K Mean '(C±C) = 0.002 A Ê R factor = 0.037 wR factor = 0.112 Data-to-parameter ratio = 25.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 27 H 39 N 3 O 9 , is a key intermediate in the synthesis of novel -turn mimetics based on electrophilic amination of enantiomerically pure (S)-pyroglutamic acid. The molecule adopts an extended conformation which is not stabilized by either intra-or intermolecular hydrogen bond