N-(tert-Butyl)-S-(4-methylphenyl)thiohydroxylamine
✍ Scribed by Mahmoudkhani, Amir H. ;Vargas-Baca, Ignacio
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 162 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Single-crystal X-ray study T = 173 K Mean '(C±C) = 0.004 A Ê R factor = 0.044 wR factor = 0.114 Data-to-parameter ratio = 16.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
trrf-Butyl and 2,6-di(tert-butyl)-4-methylphenyl (RHT) cyclopropanecarboxylates (4, 6, 24, 25) are lithiated with LiN(i-Pr), and t -BuLi, respectively. Reactions with alkyl halides, aldehydes, acyl chlorides, and heteroelectrophiles give a-substituted BHT esters which can be cleaved (t-BuOK/H,O/THF)
In the title compound, C 39 H 42 BrNO 4 S 2 Si, the Si atom shows a tetrahedral geometry. The phenyl rings attached to the Si atom form a dihedral angle of 54.9 (1) . The molecular packing is stabilized by NÐHÁ Á ÁO hydrogen bonds.