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N-(Phenylthio)-ε-caprolactam: A New Promoter for the Activation of Thioglycosides.

✍ Scribed by Sergio G. Duron; Tuelay Polat; Chi-Huey Wong


Publisher
John Wiley and Sons
Year
2004
Weight
168 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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✍ De-Cai Xiong; Li-He Zhang; Xin-Shan Ye 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 242 KB 👁 1 views

## Abstract Bromodimethylsulfonium bromide (BDMS) in combination with silver triflate provides a very efficient thiophilic promoter system, capable of activating both “disarmed” and “armed” thioglycosides for glycosidic bond formation. The usefulness of this new promoter is illustrated by a success