Enamine/imine tautomerism in α,β-unsatur
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S.-P. Lu; Anita H. Lewin
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Article
📅
1998
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Elsevier Science
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French
⚖ 549 KB
Investigation of the t~,l~-unsaturated-o~-amino acids--dehydrovaline, debydrophenylalanine, and debydropipecolinic acid---revealed that these compounds undergo rapid hydrolysis in neutral aqueous medium, via the imine tautomers, even when the corresponding esters and sodium salts exist as the enamin