Lithium diorganocuprates are now widely used in conjugate additions to a,a-unsaturated car-bony1 compounds' and in coupling reactions with alkyl halides2, allyli~acetates~, and other compounds possessing good leaving groups. Here we report a new reaction of lithium dialkylcuprates which is formally
✦ LIBER ✦
The reactions of α,β unsaturated amino imines with alkyl lithium compounds
✍ Scribed by Keith J. Fisher
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 164 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
A 'non-classical' aromatic structure was proposed by Dorman' for 2-benzylamino 4-benzylimino-2-pentene(1) Malondialdehydedianil(I1) and some close analogues were shown to have similar structures. 2 The main evidence
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## Abstract Except from 1,4,9,10‐anthracenetetrols, 9,10‐anthrahydroquinones (derived from the quinones **5a** and **18**– **21**) react with unhindered Michael acceptors such as acrylate, acrylonitrile, acrylaldehyde, and methyl vinyl ketone with addition at C‐9 or C‐10 to yield anthrones. The dir