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N-Imidoyl Isocyanides

✍ Scribed by Priv.-Doz. Dr. Gerhard Höfle; Dr. Bernd Lange


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
251 KB
Volume
16
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


N-Acyl Isocyanides
✍ Priv.-Doz. Dr. Gerhard Höfle; Dipl.-Chem. Bernd Lange 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 224 KB

**The first acyl isocyanides** have now become available. The pronounced carbonyl‐activation of benzoyl isocyanide __(1)__ is manifested, __e.g.__, in the acylation of ynamines; in contrast, __(1)__ undergoes cycloaddition with acetylenedicarboxylates. equation image

On the Synthesis of N-Sulfonyl Substitut
✍ Gerrit L'abbé; Alex van Asch; Françoise Godts 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 93 KB 👁 1 views

The high reactivity of imidoyl chlorides in nucleophilic displacement reactions is related to their facile isomerization into nitrilium ions.' with the azide ion to give imidoyl azides which may equilibrate with tetrazoles depending on the nature of the substituents, temperature and solvent used. Fo