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N-Heterocyclic Carbene−Ruthenium Complexes for the Racemization of Chiral Alcohols

✍ Scribed by Bosson, Johann; Nolan, Steven P.

Book ID
111868469
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
782 KB
Volume
75
Category
Article
ISSN
0022-3263

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ChemInform Abstract: N-Heterocyclic Carb
ChemInform Abstract: N-Heterocyclic Carbene—Ruthenium Complexes for the Racemization of Chiral Alcohols.
✍ Johann Bosson; Steven P. Nolan 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 25 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Active ruthenium-(N-heterocyclic carbene
Active ruthenium-(N-heterocyclic carbene) complexes for hydrogenation of ketones
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Four ruthenium-N-heterocyclic carbene complexes (3-6) have been prepared and the new compounds characterized by C, H, N analyses, 1 H-NMR and 13 C-NMR. The reduction of ketones to alcohols via transfer hydrogenation was achieved with catalytic amounts of complexes 3-6 in the presence of t-BuOK.