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N-Heterocyclic Carbene Rhodium Complexes and Their Reactions with H2 and with CO

✍ Scribed by Xiao-Yan Yu; Hongsui Sun; Brian O. Patrick; Brian R. James


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
351 KB
Volume
2009
Category
Article
ISSN
1434-1948

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## Abstract Mixed N‐heterocyclic carbene‐substituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free N‐heterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru