N-Fused Pentaphyrins and Their Rhodium Complexes: Oxidation-Induced Rhodium Rearrangement
✍ Scribed by Shigeki Mori; Ji-Young Shin; Soji Shimizu; Fumiaki Ishikawa; Hiroyuki Furuta; Atsuhiro Osuka
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 245 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0947-6539
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📜 SIMILAR VOLUMES
## Abstract A series of hydroxyalkyl‐functionalized imidazolium salts have been coordinated to Rh and Ir to afford the corresponding MCp\*–(NHC) (Cp\*=pentamethylcyclopentadienyl) complexes. The reactivity of the new complexes has been studied with special attention to the transformations that deal
## Abstract Mixed N‐heterocyclic carbene‐substituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free N‐heterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru