𝔖 Bobbio Scriptorium
✦   LIBER   ✦

N-Ethoxy­carbonyl-N′-phenyl­thio­urea

✍ Scribed by Zhang, You-Ming ;Wei, Tai-Bao ;Xian, Liang ;Lin, Qi ;Yu, Kai-Bei

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
132 KB
Volume
59
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, C 10 H 12 N 2 O 2 S, adopts a cis±trans con®guration, where the phenyl group and the ethoxycarbonyl moiety lie, respectively, cis and trans relative to the S atom across the thiourea CÐN bonds. Both NÐH atoms participate in intermolecular hydrogen bonds and one also forms an intramolecular hydrogen bond. The molecules in the crystal pack in alternating orientations to form ribbons.

📜 SIMILAR VOLUMES

N-Ethoxy­carbonyl-N′-(2-methyl­phenyl)­t
N-Ethoxy­carbonyl-N′-(2-methyl­phenyl)­thio­urea
✍ Lin, Qi ;Zhang, You-Ming ;Wei, Tai-bao ;Wang, Hai 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 308 KB

Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.003 A Ê R factor = 0.042 wR factor = 0.115 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

N-Benzoyl-N′-phenyl­thio­urea
N-Benzoyl-N′-phenyl­thio­urea
✍ Yamin, Bohari M. ;Yusof, M. Sukeri M. 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 287 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.045 wR factor = 0.125 Data-to-parameter ratio = 17.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

N,N′-Bis(tert-butoxy­carbonyl)­thio­urea
N,N′-Bis(tert-butoxy­carbonyl)­thio­urea
✍ Li, Cong ;Chan, Kannie Wai Yan ;Szeto, Lap 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 233 KB

The title compound, C 11 H 20 O 4 N 2 S, has a planar skeleton and its crystal structure is stabilized by extensive intermolecular (NÐHÁ Á ÁS) and intramolecular (NÐHÁ Á ÁO and CÐHÁ Á ÁO) hydrogen-bonding interactions.

N′-Benzoyl-N-p-bromo­phenyl­thio­urea
N′-Benzoyl-N-p-bromo­phenyl­thio­urea
✍ Yamin, Bohari M. ;Yusof, M. Sukeri M. 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 238 KB
N,N′-Bis(2-phenyl­ethyl)thio­urea
N,N′-Bis(2-phenyl­ethyl)thio­urea
✍ Sadiq-ur-Rehman, ;Ali, Saqib ;Parvez, Masood 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 212 KB

The structure of the title compound, C 17 H 20 N 2 S, exhibits hydrogen bonding of the type N-HÁ Á ÁS, resulting in chains of molecules running along the b axis.