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N -Demethylation of N,N -Dimethylanilines by the Benzotriazole N -Oxyl Radical: Evidence for a Two-Step Electron Transfer−Proton Transfer Mechanism

✍ Scribed by Baciocchi, Enrico; Bietti, Massimo; Lanzalunga, Osvaldo; Lapi, Andrea; Raponi, Daniele


Book ID
120049979
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
934 KB
Volume
75
Category
Article
ISSN
0022-3263

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The kinetics of the nitrosation of methyl, ethyl. propyl. butyl, and ally1 urea were studied by conventional and stopped-flow spectrophotometry in the presence or absence of acetate or mono-di-, or trichloroacetate anions In the presence of a large excess of urea, the observed rate equation was whe