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Evidence for an electron transfer mechanism in the reduction of ketones by main group metal hydrides

โœ Scribed by Ashby, Eugene C.; Goel, Anil B.; DePriest, Robert N.

Book ID
120012604
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
269 KB
Volume
102
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

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Evidence for a single electron transfer mechanism in 1he reduction of aromatic nitrogen heterocycles with main group metal hydrides and dihydropyridyl metal complexes.
โœ E.C. Ashby; A.B. Goel ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 239 KB

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The widespread use of lithium diisopropyl amide (LDA) as a strong base has revolutionized numerous facets of mechanistic and synthetic organic chemistry in recent years;' however, it is less widely appreciated that amide bases can function also as reducing agents.' LDA, for example, reduces benzophe