The title compound, C~23~H~19~ClN~2~O~2~, has been obtained by the reaction of (__Z__)-4-(4-chlorobenzylidene)-2-phenyloxazol-5(4__H__)-one and benzylamide. The molecules are connected by two N—H...O intermolecular hydrogen bonds to form helicoidal chains running parallel to the __c__ axis.
N-(Benzylaminothiocarbonyl)benzamide
✍ Scribed by Sabino, Jose R. ;Cunha, Silvio ;Bastos, Rodrigo M. ;Vencato, Ivo
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 229 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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The title compound, C 21 H 17 N 3 O 3 exhibits antifungal and antibacterial properties. The crystal structure is stabilized by a co-operative interplay of both intra-and intermolecular strong and weak hydrogen bonds of types O-HÁ Á ÁN, N-HÁ Á ÁO and C-HÁ Á ÁO/N.
In the title compound, C 21 H 25 N 3 O 2 S, the p-anisoyl group is inclined to the central thiourea N 2 CS unit by 31.939 (11) and the piperidine ring adopts a chair conformation. The molecule is stabilized by intra-and intermolecular interactions to form polymeric chains parallel to the ac plane.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.039 wR factor = 0.113 Data-to-parameter ratio = 19.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 16 H 17 N 5 O 2 S, the configuration is trans about the formal C N bond. The molecular conformation is stabilized by an intramolecular N-HÁ Á ÁN hydrogen bond.