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N-Benzyl-2-methyl­furan-3-thio­carboxanilide

✍ Scribed by Pavlović, Gordana ;Tralić-Kulenović, Vesna ;Popović, Zora


Book ID
104481703
Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
255 KB
Volume
60
Category
Article
ISSN
1600-5368

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.053 wR factor = 0.167 Data-to-parameter ratio = 15.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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A simple and convenient method for the microsynthesis of tritiated 3-methylfuran and trttiated 2-1nethylfuran froa 3furfuryl chloride and 2-furfuryl chloride, respectively, has been described. The tritium label was introduced by reductive dehalogenation with tritiated lithim aluminum hydride.

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The title compound, [Zn(C 12 H 10 N 2 O 2 S) 2 (C 2 H 6 OS)], is monomeric with the Zn atom in a ®ve-coordinate environment. The geometry of the polyhedron is distorted trigonal bipyramidal, with angles of the equatorial atoms about the central Zn atom in the range 77.84 (10)±126.66 (12) A Ê . The O