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N-Acyl-N′-arylsulfonyldiazenes; Detection and Use in the Synthesis of Amides

✍ Scribed by Dr. Hansjürgen Gölz; Dr. Bernd Glatz; Dr. Georges Haas; Dr. Günter Helmchen; Prof. Dr. Hans Muxfeldt


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
239 KB
Volume
16
Category
Article
ISSN
0044-8249

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✦ Synopsis


then treated with petroleum ether. This affords 0.26g (32 %)

( 5 a ) , m.p. 293-294°C. 0.31 g (38%) ( 3 a ) can be obtained from the petroleum ether solution by distillation.


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31P and 15N NMR spectra of 11 cyclic and non-cyclic phosphoramidates were measured. Comparison of the closely related structures demonstrated correlation between the bond angles at nitrogen and the 15N NMR chemical shifts and the 1J(P,N) coupling constants. 15N NMR parameters allowed the exo-and end