There are two molecules in the asymmetric unit of the title compound, C~10~H~11~NO~3~, an intermediate for the optical resolution of DL-phenylglycine,. The crystal packing involves intermolecular O—H...O and N—H...O hydrogen bonds.
N-Acetyl-N-phenylglycine
✍ Scribed by Fu, Ai-Yun ;Wang, Da-Qi
- Book ID
- 104484701
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 162 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The structure of the title amino acid, C 10 H 11 NO 3 , is stabilized by O-HÁ Á ÁO hydrogen bonds, connecting the molecules into infinite chains along the b axis.
📜 SIMILAR VOLUMES
The title compound, C 13 H 19 N 3 O 3 SÁH 2 O, is V-shaped and entraps a water molecule. In the crystal structure, NÐHÁ Á ÁO, OÐHÁ Á ÁO and OÐHÁ Á ÁN hydrogen bonds and van der Waals forces stabilize the packing of the molecules.
In the title compound, C~10~H~13~Cl~2~O~4~PS, all bond lengths and angles are normal. The P atom is in a distorted tetrahedral configuration. In the crystal structure, intermolecular N—H...O hydrogen bonds link the molecules into chains running along the __b__ axis.
In the crystal structure of the title compound, C 15 H 11 Cl 2 N 3 O 4 S, there are two intramolecular N-HÁ Á ÁO and one C-HÁ Á ÁS hydrogen bonds and a weak intermolecular C-HÁ Á ÁO hydrogen bond.
The title compound, C 6 H 9 NO 3 , was prepared by the nucleophilic substitution reaction of methylacryloyl chloride with glycine. Intermolecular N-HÁ Á ÁO and O-HÁ Á ÁO hydrogen bonds link the molecules into a three-dimensional network, which may be effective in stabilizing the crystal structure.