N-Acetyl-3,6-di-tert-butyl-2-(3,6-di-tert-butyl-3H-azepin-2-yl)-2,3-dihydro-1H-azepine
β Scribed by Satake, K. ;Hattori, T. ;Kimura, M. ;Kashino, S.
- Book ID
- 114512338
- Publisher
- International Union of Crystallography
- Year
- 1995
- Tongue
- English
- Weight
- 420 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0108-2701
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## Abstract Different photochemical behavior between 3,6β and 2,5βdiβ__t__βbutylβ3__H__βazepine was observed. The former gave wavelength dependent products 3,5βdiβ__t__βbutylpyridine on irradiation through Pyrex filter __via__ photolysis and 4,7βdiβ__t__βbutylβ2βazabicyclo[3.2.0]heptaβ2,6βdiene on
The Reactions of 3,6-Di-tert-butyl-1,2-benzoquinone and 3,6-Ditert-butylcatechol with tert-Butyl Hydroperoxide. -The reaction of the title quinone (I) as well as its corresponding catechol with tert-butyl hydroperoxide in aprotic solvents results in ring oxidation accompanied by ring expansion furn