𝔖 Bobbio Scriptorium
✦   LIBER   ✦

N-[4-Cyano-3-(trifluoro­meth­yl)phen­yl]-3-(4-fluoro­phenyl­sulfon­yl)-2-hydr­oxy-2-methyl­propionamide

✍ Scribed by Hu, Xiu-Rong ;Gu, Jian-Ming

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
254 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The structure of the title compound, C 18 H 14 F 4 N 2 O 2 S, consists of molecules that pack in a linear hydrogen-bonded chain along the c axis. This hydrogen-bonding arrangement involves the hydroxy group and one of the sulfonyl O atoms.

📜 SIMILAR VOLUMES

N-[4-Cyano-3-(trifluoro­meth­yl)phen­yl]
N-[4-Cyano-3-(trifluoro­meth­yl)phen­yl]-3-(4-fluoro­phenyl­sulfan­yl)-2-hydr­oxy-2-methyl­propionamide
✍ Hu, Xiu-Rong ;Wang, Li-Li ;Gu, Jian-Ming 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 201 KB

Single-crystal X-ray study T = 296 K Mean (C-C) = 0.004 A Disorder in main residue R factor = 0.065 wR factor = 0.175 Data-to-parameter ratio = 16.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

2,2-Dichloro-N-{[1-(fluoro­meth­yl)-2-hy
2,2-Dichloro-N-{[1-(fluoro­meth­yl)-2-hydr­oxy-2-[4-(methyl­sulfon­yl)phen­yl]ethyl}­acetamide
✍ Cheng, Jing ;Wang, Neng-Xue ;Yang, Guang-Fu 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 308 KB

The crystal structure of the title compound, C 12 H 14 Cl 2 FNO 4 S, shows that, although there are no intra-or intermolecularstacking interactions, there are O-HÁ Á ÁO, C-HÁ Á ÁF and C-HÁ Á ÁO hydrogen bonds.

N-(3-Chloro­phen­yl)-2-cyano-3-(4-hydr­o
N-(3-Chloro­phen­yl)-2-cyano-3-(4-hydr­oxy-3-meth­oxy-2-nitro­phen­yl)prop-2-enamide
✍ Zheng, Xian-Ming ;Hu, Wei-Xiao ;Xu, Feng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 257 KB

In the title compound, C~17~H~12~ClN~3~O~5~, the benzene rings are twisted out of the central –C~ar~–C–C(–CN)–C(=O)–N–plane. The dihedral angles between this plane and the aromatic planes are 31.2 (4) and 4.8 (3)°. The C=C double bond is in an __E__ configuration.

4-{(2,4-Dichloro­phen­yl)[5-hydr­oxy-1-p
4-{(2,4-Dichloro­phen­yl)[5-hydr­oxy-1-phenyl-3-(tri­fluoro­meth­yl)-1H-pyrazol-4­yl]meth­yl}-1-phenyl-3-(trifluoro­meth­yl)-1H-pyrazol-5-ol monohydrate
✍ Yao, Chang-Sheng ;Yu, Chen-Xia ;Tu, Shu-Jiang ;Wang, Xiang-Shan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 214 KB

The title compound, C 27 H 16 Cl 2 F 6 N 4 O 2 ÁH 2 O, was obtained by the reaction of 2,4-dichlorobenzaldehyde and 2-phenyl-5trifluoromethyl-2H-pyrazol-3-ol in aqueous media without any catalyst. In the crystal structure, both intra-and intermolecular hydrogen bonds are found.

N-(4-Meth­oxy-6-methyl-1,3,5-triazin-2-y
N-(4-Meth­oxy-6-methyl-1,3,5-triazin-2-yl)-N-methyl-N′-(2,3,4-trifluoro­phen­yl)urea
✍ Chen, Sheng-Chun ;He, Ming-Yang ;Zhu, Hong-jun ;Chen, Qun 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 265 KB

In the title compound, C 13 H 12 F 3 N 5 O 2 , intramolecular N-HÁ Á ÁF, N-HÁ Á ÁN, C-HÁ Á ÁO and C-HÁ Á ÁN hydrogen bonds, andstacking interactions generate a columnar structure along the a axis.

2-{[2-Chloro-5-(4-methoxy­phen­yl)pyridi
2-{[2-Chloro-5-(4-methoxy­phen­yl)pyridin-3-yl](hydr­oxy)meth­yl}acrylonitrile
✍ Swamy, G. Y. S. K. ;Ravikumar, K. ;Narender, P. ;Rao, V. Jayathirtha 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 220 KB

In the title compound, C 16 H 13 ClN 2 O 2 , the dihedral angle between the pyridine and benzene rings is 40.1 (1) . There is a weak intramolecular C-HÁ Á ÁCl interaction. Molecules are linked via O-HÁ Á ÁN hydrogen bonds, forming chains of graph-set motif C(6) along the a axis.