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N-(4-Chlorophenyl)-2,2,2-trimethylacetamide

✍ Scribed by Gowda, B. Thimme ;Foro, Sabine ;Fuess, Hartmut


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
130 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The structure of the title compound, C 11 H 14 ClNO, is closely related to the ring-unsubstituted 2,2,2-trimethyl-N-phenylacetamide and 2,2,2-trimethyl-N-(4-methylphenyl)acetamide with slightly different bond parameters. The molecules are linked into chains running along the b-axis direction through N-HÁ Á ÁO hydrogen bonding.


πŸ“œ SIMILAR VOLUMES


N-(2-Chlorophenyl)-2,2,2-trimethylacetam
✍ Gowda, B. Thimme ;Svoboda, Ingrid ;Fuess, Hartmut πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 576 KB
N-(3-Chlorophenyl)-2,2,2-trimethylacetam
✍ Gowda, B. Thimme ;Foro, Sabine ;Fuess, Hartmut πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 123 KB

In the structure of the title compound (3CPTMA), C 11 H 14 ClNO, the conformation of the N-H bond is anti to the meta-chloro substituent, similar to that observed for the corresponding meta-methyl-substituted amide. The bond parameters of the two amides are also similar. The molecules in 3CPTMA are

N-(3,5-Dichlorophenyl)-2,2,2-trimethylac
✍ Gowda, B. Thimme ;KoΕΎΓ­Ε‘ek, Jozef ;Tokarčík, Miroslav ;Fuess, Hartmut πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 219 KB

Molecules of the title compound, C 11 H 13 Cl 2 NO, are linked into a chain running along the b-axis direction. The structure shows a close resemblance to those of related amides but with slightly different bond parameters.

N-(4-Chlorophenyl)-2-nitrobenzamide
✍ Saeed, Aamer ;Hussain, Shahid ;Bolte, Michael πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 258 KB
2-Chloro-N-(4-chlorophenyl)acetamide
✍ Gowda, B. Thimme ;Foro, Sabine ;Fuess, Hartmut πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 422 KB

The structure of the title compound, C~8~H~7~Cl~2~NO, resembles those of __N__-(4-chlorophenyl)acetamide, __N__-2-chloro-(4-methylphenyl)acetamide, __N__-2-chloro-(4-nitrophenyl)acetamide and other related amides, with similar bond parameters. Molecules are linked into chains through Nβ€”H...O hydroge