N-(4-Chlorophenyl)-2,2,2-trimethylacetamide
β Scribed by Gowda, B. Thimme ;Foro, Sabine ;Fuess, Hartmut
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 130 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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β¦ Synopsis
The structure of the title compound, C 11 H 14 ClNO, is closely related to the ring-unsubstituted 2,2,2-trimethyl-N-phenylacetamide and 2,2,2-trimethyl-N-(4-methylphenyl)acetamide with slightly different bond parameters. The molecules are linked into chains running along the b-axis direction through N-HΓ Γ ΓO hydrogen bonding.
π SIMILAR VOLUMES
In the structure of the title compound (3CPTMA), C 11 H 14 ClNO, the conformation of the N-H bond is anti to the meta-chloro substituent, similar to that observed for the corresponding meta-methyl-substituted amide. The bond parameters of the two amides are also similar. The molecules in 3CPTMA are
Molecules of the title compound, C 11 H 13 Cl 2 NO, are linked into a chain running along the b-axis direction. The structure shows a close resemblance to those of related amides but with slightly different bond parameters.
The structure of the title compound, C~8~H~7~Cl~2~NO, resembles those of __N__-(4-chlorophenyl)acetamide, __N__-2-chloro-(4-methylphenyl)acetamide, __N__-2-chloro-(4-nitrophenyl)acetamide and other related amides, with similar bond parameters. Molecules are linked into chains through NβH...O hydroge