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N-(3,5-Dichlorophenyl)-2,2,2-trimethylacetamide

✍ Scribed by Gowda, B. Thimme ;Kožíšek, Jozef ;Tokarčík, Miroslav ;Fuess, Hartmut

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 219 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807013980

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✦ Synopsis

Molecules of the title compound, C 11 H 13 Cl 2 NO, are linked into a chain running along the b-axis direction. The structure shows a close resemblance to those of related amides but with slightly different bond parameters.

📜 SIMILAR VOLUMES

N-(3-Chlorophenyl)-2,2,2-trimethylacetam

N-(3-Chlorophenyl)-2,2,2-trimethylacetamide

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In the structure of the title compound (3CPTMA), C 11 H 14 ClNO, the conformation of the N-H bond is anti to the meta-chloro substituent, similar to that observed for the corresponding meta-methyl-substituted amide. The bond parameters of the two amides are also similar. The molecules in 3CPTMA are

N-(2-Chlorophenyl)-2,2,2-trimethylacetam

N-(2-Chlorophenyl)-2,2,2-trimethylacetamide

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N-(4-Chlorophenyl)-2,2,2-trimethylacetam

N-(4-Chlorophenyl)-2,2,2-trimethylacetamide

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The structure of the title compound, C 11 H 14 ClNO, is closely related to the ring-unsubstituted 2,2,2-trimethyl-N-phenylacetamide and 2,2,2-trimethyl-N-(4-methylphenyl)acetamide with slightly different bond parameters. The molecules are linked into chains running along the b-axis direction through

N-(2,5-Dichlorophenyl)acetamide

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2,2-Dichloro-N-(2,3-dichlorophenyl)aceta

2,2-Dichloro-N-(2,3-dichlorophenyl)acetamide

✍ Gowda, B. Thimme ;Foro, Sabine ;Fuess, Hartmut 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 567 KB

The conformation of the N-H bond in the title compound, C 8 H 5 Cl 4 NO, is syn to the 2-chloro substituent in the aromatic ring, similar to that of the 2-chloro substituent in 2,2-dichloro-N-(2-chlorophenyl)acetamide, the 3-chloro substituent in 2,2dichloro-N-(3,4-dichlorophenyl)acetamide and the 2

N-(2,3-Dichlorophenyl)acetamide

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