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N-(3,5-Dichlorophenyl)methanesulfonamide

✍ Scribed by Gowda, B. Thimme ;Foro, Sabine ;Fuess, Hartmut


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
644 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The structure of the title compound, C 7 H 7 Cl 2 NO 2 S, resembles those of other methanesulfonanilides, with similar geometric parameters. The amide H atom is roughly in the plane of the dichlorophenyl group with a deviation of Γ€0.021 (7) A ˚, while the S atom is slightly above the plane with a deviation of 0.285 (9) A ˚. The dihedral angle between the benzene ring and the C-N-S plane is 14.4 (5) . The molecules are packed into chains through N-HÁ Á ÁO hydrogen bonds and weak (methyl)C-HÁ Á ÁO interactions.


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Molecules of the title compound, C 11 H 13 Cl 2 NO, are linked into a chain running along the b-axis direction. The structure shows a close resemblance to those of related amides but with slightly different bond parameters.

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