In the title compound, C 22 H 20 N 4 O 5 , the central vanillin group makes dihedral angles of 4.44 (11) and 60.33 (6) with the pyridine and other benzene rings. The crystal packing is stabilized by N-HÁ Á ÁN hydrogen bonds and C-HÁ Á ÁO interactions, leading to an infinite network.
N′-(3-Ethoxy-4-hydroxybenzylidene)isonicotinohydrazide
✍ Scribed by Qian, Heng-Yu ;Yin, Zhi-Gang ;Jia, Jia ;Liu, Sheng-Min ;Feng, Ling-Qin
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 143 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C 13 H 11 N 3 O 2 , was prepared by the reaction of pyridine-4-carboxylic acid hydrazide and phydroxybenzaldehyde in ethanol. In the crystal structure, all non-H atoms are coplanar, with an r.m.s. deviation of 0.096 A ˚. N-HÁ Á ÁN, O-HÁ Á ÁN and O-HÁ Á ÁO intermolecular hydrogen
The asymmetric unit of the title compound, C~14~H~13~N~3~O~3~·H~2~O, contains one molecule of __N__′-(4-hydroxy-3-methoxybenzylidene)isonicotinohydrazide and one solvent water molecule. The crystal packing is stabilized by O—H...N and O—H...O hydrogen bonds.
In the title compound, C 17 H 18 N 2 O 3 , the isovanillin group makes a dihedral angle of 9.63 (11) with the plane of the terminal phenyl ring. Intermolecular N-HÁ Á ÁO hydrogen bonds help to consolidate the crystal packing.
The bond lengths in the title compound, C 13 H 11 N 3 O 2 ÁH 2 O indicate that the organic molecule exists in the keto form. A network of O-HÁ Á ÁO, O-HÁ Á ÁN and N-HÁ Á ÁO hydrogen bonds helps to consolidate the crystal packing.