N-(1-cyano-d-glycosyl)amides — Novel anomeric α-amino-acid derivatives
✍ Scribed by Viktor Gyóllai; László Somsák; László Szilágyi
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 247 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
In the presence of basic silver salts C-(l-bromo-1-deoxy-D-glycopyranosyl)formamides and various nitriles applied as solvents give N-(l-cyano-D-glycopyranosyl)amides in a highly stereoselective reaction.
📜 SIMILAR VOLUMES
Two new glycosyl amino acids N'~-Fmoc-Ser[Ac4-fl-D-Galp-(1 ~ 3)-Ac2-a-D-GalN3P]-OPf p and N'~-Fmoc-Thr[Ac4-/3-D-Galp-(1 ~ 3)-Ac2-a-D-GalN3p]-OPf p were synthesized. Glycosylation of N'~-Fmoc-Ser-OPf p or N ~-Fmoc-Thr-OPfp with protected/3-o-Gal-( 1 -~ 3)-D-GaIN 3 donors afforded the glycosyl amino a
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