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Mössbauer spectroscopic study of the magnetic relaxation in tris(β-diketonato)iron(III) complexes

✍ Scribed by S. Yamauchi; Y. Sakai; H. Nishioji; T. Tominaga


Publisher
Elsevier Science
Year
1983
Weight
267 KB
Volume
34
Category
Article
ISSN
0020-708X

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Magnetic suswptibilities down to 1.2"K and 57Fe Miissbauer spectra at 42°K are reported on [Fe(pten)2 OR] \* 5H20. The results are consistent with a 3Az(~z~2~~)ground state characterized by a zero-field splitting of D = 4.150 cm-' into an upper !&Ys= +l) and a lower 10) level andg = 2.80. In reasona