𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Mössbauer investigation of iron in aluminium—I. Al-Fe samples

✍ Scribed by S. Nagy; A. Vértes; Z. Homonnay; L. Murgás


Publisher
Elsevier Science
Year
1987
Weight
594 KB
Volume
35
Category
Article
ISSN
0001-6160

No coin nor oath required. For personal study only.

✦ Synopsis


An AI--O.58 m% Fe billet was cast by semicontinuous method (melt temperature: 685'C, casting speed: 80 mm!min). The intermetallic AiFe phases formed during casting and subsequent heat treatments were investigated by Miissbauer spectroscopy. The Miissbauer parameters of the iron-containing species (i.e. dissolved iron, A&Fe and Ai,Fe) occurring in the specimens were determined by the measurement of samples specially prepared for that purpose. Possible problems of phase analysis such as the apparent orientation of Al, Fe crystaiiites were also considered and discussed. The Miissbauer spectra indicated that initially the cast ahoy contained only A&Fe besides AI solid solution. Heat treatments performed at 450 and 530°C caused only some broadening in the spectrum iines of A&Fe, but at 620°C A&Fe transformed completely to A&Fe after IO-15 h.


📜 SIMILAR VOLUMES


Mössbauer investigation of the transform
✍ Daniel C. Melchior; T.R. Wildeman; D.L. Williamson 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 859 KB

Iron phases in raw and retorted shales have been studied from the TOSCO II, Paraho, and Lawrence Livermore Laboratory (LLL) 125 kg retorting processes by MGssbauer effect spectroscopy. Using the Mijssbauer effect, changes in the iron mineralogy during retorting were monitored. Results show that the

The problem of spin triplet states of ir
✍ E. König; P. Gütlich; R. Link 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 310 KB

Bath thcoreticai and experimental evidence is presented to demonstrate that doublet C previously observed in the j7Fe hfb'ssbauer emission spectrum of [Co(phen)3] CCIOJ)~.XI~O is mcst uniikely to originate in 3 spin triplet pound stare of iron(X). Rather doublets C and B are assigned to the intact [