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Mössbauer effect study of anapaite, Ca2Fe2+(PO4)2 · 4H2O, and of its oxidation products

✍ Scribed by S. G. Eeckhout; E. De Grave; R. Vochten; N. M. Blaton


Publisher
Springer-Verlag
Year
1999
Tongue
English
Weight
367 KB
Volume
26
Category
Article
ISSN
0342-1791

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✍ L. Asch; I. Dézsi; T. Lohner; B. Molnár 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 205 KB

The Miissbauer spectra of iron and cobalt fluoroborate hexahydrate show a change by a factor of two in the quadrupole interaction near 2%) K and 185 K, respectively, togtther with a sudden drop in resonance fraction. This behaviour is explained as a first order phase transition in which the axial pa