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Mössbauer effect studies of high-spin(5T2) ⥂ low-spin(1A1) transitions in frozen solutions of iron(II) complexes—II: tris(2-methyl-1,10-phenanthroline)iron(II) tetrafluoroborate

✍ Scribed by E. König; G. Ritter; H.A. Goodwin


Book ID
115974707
Publisher
Elsevier Science
Year
1977
Weight
376 KB
Volume
39
Category
Article
ISSN
0022-1902

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📜 SIMILAR VOLUMES


Thermally induced high-spin (5T2) ⇌ low-
✍ E. König; G. Ritter; H.A. Goodwin 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 403 KB

Employmg snmplcs cnrichcd to >90% in 57Fc, hlbssbducr cffcct studlcs dcmonstratc that high-spin (%2) := low-spm ('A1) transitions arc responsible for the peculiar tempcraturc dcpendcncc of the mdgnctlsm in ccrtam [fc(paptH)z ] X2 l nH20 complcxcs where paptH = 2-(2-pyridyhho) -4-(2-pyrldyl)thiai!olc

Hyperfine interactions at a cooperative
✍ E. König; G. Ritter; R. Zimmermann 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 333 KB

Hyperfine interactions have been studied at a cooperative 'T2 = ' Al transition in the solid complex Fe(4,7-(CH&-pher&(NCS)z employing an external field Helt = 40 kG and temperatures between 4.2 and 163OK (phen = l,iO-phenanthroline). At cryogenic temperatures, the isolated 'Al ground state may be