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Mössbauer Effect and X-ray Studies of the Phase Transitions in K 2 Fe(SO 4 ) 2 ·nH 2 O(n=2,4,6)

✍ Scribed by Ishigami, H.; Niida, H.; Hikita, T.; Sato, S.; Shiro, M.; Hori, T.

Book ID
127041215
Publisher
Taylor and Francis Group
Year
2002
Tongue
English
Weight
243 KB
Volume
269
Category
Article
ISSN
0015-0193

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✍ L. Asch; I. Dézsi; T. Lohner; B. Molnár 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 205 KB

The Miissbauer spectra of iron and cobalt fluoroborate hexahydrate show a change by a factor of two in the quadrupole interaction near 2%) K and 185 K, respectively, togtther with a sudden drop in resonance fraction. This behaviour is explained as a first order phase transition in which the axial pa