Myoglobin-catalyzed epoxidation of styrene in organic solvents accelerated by bioimprinting
β Scribed by Shinji Ozawa; Alexander M. Klibanov
- Book ID
- 110226720
- Publisher
- Springer Netherlands
- Year
- 2000
- Tongue
- English
- Weight
- 45 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0141-5492
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π SIMILAR VOLUMES
Ferric ion-catalyzed cycloaddition of styrene derivatives with quinone gave 2,3-dihydrobenzofuran derivatives in excellent yields with trans selectivity; remarkable acceleration was observed when the reaction was carried out in an ionic liquid solvent system.
The effects of 18-crown-6 on the synthesis of peptides catalyzed by β£-chymotrypsin are reported. Lyophilization of the enzyme in the presence of 50 equivalents of 18-crown-6 results in a 425-fold enhanced activity when the reaction between the 2-chloroethylester of N-acetyl-L-phenylalanine and L-phe