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Mutual Interdependence of Spin Crossover and Metal−Metal Bond Formation in M 2 Cl 93- (M = Fe, Ru, Os)

✍ Scribed by Lovell, Timothy; Stranger, Robert; McGrady, John E.

Book ID
120549605
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
64 KB
Volume
40
Category
Article
ISSN
0020-1669

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## Abstract The reductive carbonylation of ruthenium and osmium halides in the presence of cobalt and iron surfaces was studied. In these surface‐assisted reactions the metal surface plays an active role in releasing metal ions, which can be used for the in situ synthesis of mixed‐metal compounds.