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Mutual diffusion coefficients in concentrated electrolyte solutions

✍ Scribed by J.F. Dufrêche; O. Bernard; P. Turq

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
827 KB
Volume
96-97
Category
Article
ISSN
0167-7322

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📜 SIMILAR VOLUMES

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Mutual diffusion coefficients in electrolyte solutions
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In this paper the mutual diffusion coefficients of LiCl, NaCl and KC1 in aqueous solutions are calculakd for a large range of concellt,rations (up to 1M) using the Hypernetted Chain (HNC) a.nd Mean Spherical (MSA) approximations at the MC Millan Mayer level. The theoretical results are compared with

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Molecular dynamics simulations on Lennard-Jones mixture in the supercritical region are performed. The number of the molecules in the unit cell is 23328 and the mole fraction is 0.5. The concentration fluctuations near the critical point are large compared to the ideal mixing. The mutual diffusion c