Predicting ability of free-volume theory
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Seong-Uk Hong
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Article
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1996
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John Wiley and Sons
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English
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The effect of solvent size on the diffusion process is studied for various solvents with natural rubber and polybutadiene in terms of the free-volume theory. The importance of energy effects on the diffusion of penetrants in rubbers is examined. The critical molar volume of the polymer jumping unit