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Solvent self-diffusion in the system polystyrene-ethylbenzene in terms of the modified free-volume theory

โœ Scribed by O. E. Zgadzai; A. I. Maklakov


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
288 KB
Volume
36
Category
Article
ISSN
0323-7648

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Several versions of free-volume theory have been proposed to correlate or predict the solvent diffusion coefficient of a polymer/solvent system. The quantity of free volume is usually determined by the Williams-Landel-Ferry (WLF) equation from viscosity data of the pure component in these theories.