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Multitechnique Investigation of Conformational Features of Small Molecules: the Case of Methyl Phenyl Sulfoxide

✍ Scribed by Celebre, Giorgio; Cinacchi, Giorgio; De Luca, Giuseppina; Giuliano, Barbara M.; Iemma, Francesca; Melandri, Sonia


Book ID
126118438
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
200 KB
Volume
112
Category
Article
ISSN
0022-3654

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## Abstract ^13^C‐NMR. and He (IΞ±) photoelectron spectra of alkyl phenyl sulfides, sulfoxides and sulfones have been used to probe how their conformations depend on the size of the alkyl groups R. The results are interpreted to indicate that in the sulfides the S, R‐bond is twisted out of the plana