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Multipulse Initiation in Pulsed Laser and Quenched Instationary Polymerization: Determination of the Propagation and Termination Rate Coefficients for Dicyclohexyl Itaconate Polymerization

✍ Scribed by Vana, Philipp; Yee, Lachlan H.; Davis, Thomas P.


Book ID
126790943
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
101 KB
Volume
35
Category
Article
ISSN
0024-9297

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Pulsed laser polymerization experiments have been performed on the bulk polymerization of dimethyl itaconate over the temperature range 20 -50 Β°C. The activation energy and frequency factor were calculated as 24.9 kJ/mol Οͺ1 and 2.15 Ο« 10 5 L/mol Οͺ1 s Οͺ1 , respectively. The activation energy is compa

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## Abstract **Summary:** A method for simultaneous determination of both the addition and fragmentation rate coefficients of the RAFT equilibrium reactions is presented, which is based on laser single pulse initiation in conjunction with microsecond time‐resolved ESR spectroscopy. The build‐up and