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Determination of Intramolecular Chain Transfer and Midchain Radical Propagation Rate Coefficients for Butyl Acrylate by Pulsed Laser Polymerization

✍ Scribed by Hutchinson, Robin A.; Buback, Michael; Nikitin, Anatoly N.; Hesse, Pascal


Book ID
115545837
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
340 KB
Volume
40
Category
Article
ISSN
0024-9297

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Determination of Propagation Rate Coeffi
✍ Anatoly N. Nikitin; Patrice Castignolles; Bernadette Charleux; Jean-Pierre Vairo πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 135 KB

## Abstract Unusual difficulties are faced in the determination of propagation rate coefficients (__k__~p~) of alkyl acrylates by pulsed‐laser polymerization (PLP). When the backbiting is the predominant chain transfer event, the apparent __k__~p~ of acrylates determined in PLP experiments for diff