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Determination of Propagation Rate Coefficients by Pulsed-Laser Polymerization for Systems with Rapid Chain Growth: Vinyl Acetate

✍ Scribed by Hutchinson, R. A.; Richards, J. R.; Aronson, M. T.

Book ID: 120175997
Publisher: American Chemical Society
Year: 1994
Tongue: English
Weight: 786 KB
Volume: 27
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma00094a016

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## Abstract Unusual difficulties are faced in the determination of propagation rate coefficients (__k__~p~) of alkyl acrylates by pulsed‐laser polymerization (PLP). When the backbiting is the predominant chain transfer event, the apparent __k__~p~ of acrylates determined in PLP experiments for diff