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Multiple Rhodium-Catalyzed Cleavages of Single C–C bonds
✍ Scribed by Aïssa, Christophe; Crépin, Damien; Tetlow, Daniel J.; Ho, Kelvin Y. T.
- Book ID
- 119962623
- Publisher
- American Chemical Society
- Year
- 2013
- Tongue
- English
- Weight
- 296 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1523-7060
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📜 SIMILAR VOLUMES
Acetylacetonatorhodiumolefin systems, allylrhodium complexes, or (Ph~3~P)~3~RhCl catalyzed the conversion of alkenes and molecular oxygen to carbonyl compounds __via__ CC‐bond cleavage. For example, 2,3‐dimethyl‐2‐butene was transformed into acetone. Butadiene and isoprene also undergo oxidative C
Of the variety of synthetic transformations mediated by transition metals, catalytic processes involving cleavage of C À C single bonds are among the most difficult to achieve. [1] Hence, their development remains an important challenge in organic chemistry. We recently found that the bond between t