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Multiple 1,2,3-thiadiazoles

✍ Scribed by Mousa Al-Smadi; Norbert Hanold; Herbert Meier


Publisher
Journal of Heterocyclic Chemistry
Year
1997
Tongue
English
Weight
553 KB
Volume
34
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

A series of compounds 3a‐d,i‐n with two or three 1,2,3‐thiadiazole rings, useful for photocrosslinking processes, was prepared from the di‐ or triketones 1a‐d,i‐n via the corresponding hydrazones 2a‐d,i‐n by applying the Hurd‐Mori method. A special synthetic sequence, 1e, 2e, 3e, 3f/3g, was elaborated for the olefinic system 3h.


📜 SIMILAR VOLUMES


1,2,3-Thiadiazoles
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## Abstract Die Photolyse der 1,2,3‐Thiadiazol‐2‐oxide **2** ergibt hauptsächlich die isomeren 3‐Oxide **6** und die und die 1,2,3‐Thiadiazole **1**. Die intramolekularen Cycloadditionsmechanismen für die Ringgerüstumlagerung sowie die Eigenschaften der 1,2,3‐Thiadiazol‐3‐oxide **6** werden ausführ

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A method of preparation for the title compounds 5, by bromination-dehydrobromination of the corresponding 5-alkyl-1,2,3-thiadiazoles 3, their spectroscopical characterization, and the reaction of 5 with 4-phenyl-4H-l,2,4-triazole-3,5-dione (6) with formation of 7, 8 is described. 1,2,3-Thiadiazole