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Multiphase-Separated Polyurethanes Studied by Micro-Raman Spectroscopy

✍ Scribed by Helena Janik; Barbara Pałys; Zoran S. Petrovic


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
116 KB
Volume
24
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

Micro‐Raman spectroscopy has been used to investigate the chemical micro‐heterogeneity of multiphase‐separated poly(ether urethanes) (PETU). Analysis of PETU cross‐sections by means of micro‐Raman spectroscopy revealed the nearly complete absence of soft segments in AI aggregates (called globules). These aggregates are in the order of a few micrometers in size. The composition of the matrix and the AII aggregates (spherulites) was comparable.

Example of an AFM image (sample 706, scan size 25 μm, converted to monochromatic image).

magnified imageExample of an AFM image (sample 706, scan size 25 μm, converted to monochromatic image).


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