Multinuclear NMR spectroscopic studies of some organometallic N-substituted anilines
✍ Scribed by Brian K. Barr; Amy J. Herman; Lori K. Myers; Pamela I. Young; Charles D. Schaeffer Jr.; Hilary J. Eppley; Julie C. Otter; Claude H. Yoder
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 561 KB
- Volume
- 434
- Category
- Article
- ISSN
- 0022-328X
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## Abstract ^1^H, ^13^C, ^15^N, ^29^Si and ^119^Sn NMR data (chemical shifts and coupling constants) are reported for the organometallic substituted enamines Me~3~Sn(Me~3~M)CC(NEt~2~)CH~2~OMe [M = Sn (1), Ge (2), Si (3)], of which 2 and 3 are obtained as a mixture of __E__ and __Z__ isomers, and (
## Abstract The analysis of ^15^N chemical shift data from over a hundred anilines, __N__‐methyl anilines, __N__,__N__‐dimethyl anilines and phenylhydrazines with substituents in the phenyl ring leads to an empirical equation, δ~cal~ = δon + Δ__o__ + Δ__m__ + Δ__p__, for calculating ^15^N NMR chemi