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A study of the 15N NMR chemical shifts in substituted anilines and phenylhydrazines, and their derivatives

✍ Scribed by Linsheng Li; Lina Zhang; Yunjun Lan; Changhui Zhang

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
88 KB
Volume
46
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The analysis of ^15^N chemical shift data from over a hundred anilines, N‐methyl anilines, N,N‐dimethyl anilines and phenylhydrazines with substituents in the phenyl ring leads to an empirical equation, δ~cal~ = δon + Δ__o__ + Δ__m__ + Δ__p__, for calculating ^15^N NMR chemical shifts of the amino group. This equation is based on a linear regression analysis using eighteen substituent parameters and leads to good conformity with the expected data. Copyright © 2008 John Wiley & Sons, Ltd.

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