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Multicomponent Synthesis of Chiral Sulfinimines

✍ Scribed by Dr. Caroline Roe; Dr. Heather Hobbs; Dr. Robert A. Stockman

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 150 KB
Volume: 17
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.201003222

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📜 SIMILAR VOLUMES

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

ChemInform Abstract: Synthesis of Nonrac

ChemInform Abstract: Synthesis of Nonracemic β-Amino Acids via Chiral Sulfinimines

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ChemInform Abstract: Convenient Synthesi

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ChemInform Abstract: Asymmetric Synthesi

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The diastereomerically pure sulfinylating reagent (III) reacts with nucleophilic Grignard reagents or the zinc reagent derived from (VI) to yield chiral sulfoxides with excellent yields and enantioselectivities. Under specific conditions sequential reaction of (III) with LiN(Tms)2 followed by aldehy

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## Abstract Bicyclic, tricyclic, tetracyclic and spirocyclic oxazolo‐ and oxazinopiperidines are prepared by the reaction of acids (I) or (XV) with 1,2‐ or 1,3‐amino alcohols under syngas atmosphere and microwave irradiation.