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ChemInform Abstract: Rhodium-Catalyzed Multicomponent Synthesis of Chiral Oxazolopiperidines.

✍ Scribed by Jessica Salvadori; Etienne Airiau; Nicolas Girard; Andre Mann; Maurizio Taddei

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201039154

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✦ Synopsis

Abstract

Bicyclic, tricyclic, tetracyclic and spirocyclic oxazolo‐ and oxazinopiperidines are prepared by the reaction of acids (I) or (XV) with 1,2‐ or 1,3‐amino alcohols under syngas atmosphere and microwave irradiation.

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## Abstract The reaction applies a HCOOH/NEt~3~ mixture as a hydrogen source and a chiral Rh‐complex as a catalyst.