Most research and all publications in mass spectrometry address either applications or practical questions of procedure. This book, in contrast, discusses the fundamentals of mass spectrometry. Since these basics (physics, chemistry, kinetics, and thermodynamics) were worked out in the 20th centur
Multicoincidence mass spectrometry of core excited molecules
✍ Scribed by Marc Simon; Michel Lavollée; Michael Meyer; Paul Morin
- Book ID
- 103738293
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 413 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0368-2048
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Ion trap tandem mass spectrometry of biological molecules using wide range excitation CID Product ion spectra obtained by ion trap tandem mass spectrometry (MS n ) are often very simple owing to the low-energy characteristic of the resonant excitation used for collision-induced dissociation (CID). 1
The Auger spectra of SiH4 have been measured at photon energies of 103.4, 130, and 160 eV. In the resonance (spectator) Auger spectrum, the peaks shift by 6.5 + 0.2 eV to the higher-energy side. The peak intensities for the resonance Auger lines suggest Rydberg character for the 4sa, core-excited st